Influence of Alkyl Side Chain on the Crystallinity and Trap Density of States in Thiophene and Thiazole Semiconducting Copolymer Based Inkjet-Printed Field-Effect Transistors
DC Field | Value | Language |
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dc.contributor.author | Lee, Jiyoul | - |
dc.contributor.author | Chung, Jong Won | - |
dc.contributor.author | Jang, Jaeman | - |
dc.contributor.author | Kim, Do Hwan | - |
dc.contributor.author | Park, Jeong-Il | - |
dc.contributor.author | Lee, Eunkyung | - |
dc.contributor.author | Lee, Bang-Lin | - |
dc.contributor.author | Kim, Joo-Young | - |
dc.contributor.author | Jung, Ji Young | - |
dc.contributor.author | Park, Joon Seok | - |
dc.contributor.author | Koo, Bonwon | - |
dc.contributor.author | Jin, Yong Wan | - |
dc.contributor.author | Kim, Dae Hwan | - |
dc.date.accessioned | 2022-07-16T10:20:49Z | - |
dc.date.available | 2022-07-16T10:20:49Z | - |
dc.date.created | 2021-05-13 | - |
dc.date.issued | 2013-04 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/162994 | - |
dc.description.abstract | The influence of alkyl side chains on the crystallinity of semiconducting copolymer films and their sub-bandgap density-of-states (DOS), the latter being closely related to the stability and the device performance of organic field-effect transistors (OFETs), is investigated Three different poly(hexathiophene-alt-bithiazole) (PFITBTz) based polymer semiconductors, with identical backbones but different side chain positions and lengths, were synthesized The crystallinity examined by grazing incidence X-ray diffraction (GIXRD) strongly depends on the number, position, and length of each type of alkyl side chain attached to the thiophene and thiazole copolymer backbones Also, the sub-bandgap trap DOS distributions were extracted by performing multiple frequency capacitance voltage (MF-CV) spectroscopy on the field effect devices. The relationship between film crystallinity and trap DOS in the field-effect transistors can be interpreted in terms of the complex interplay between the number, position, and length of each alkyl side chain for efficient pi-pi stacking. In particular, the number and position of the alkyl side chain attached to the polymer backbone significantly affects the device performance. Poly(tetryloctylhexathiophene-alt-dioctylbithiazole) (PHTBTz-C8) exhibits the best electrical performance among the different semiconductors synthesized, with a relatively low bulk trap density of similar to 2.0 x 10(20) cm(-2) eV(-1) as well as reasonable hole mobility of similar to 0.25 cm(2) s(-1). The microstructural analyses of this organic material strongly suggest that the short pi-pi stacking distance induces strong interaction between adjacent polymer backbones, which in turn results in enhanced electrical properties. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Influence of Alkyl Side Chain on the Crystallinity and Trap Density of States in Thiophene and Thiazole Semiconducting Copolymer Based Inkjet-Printed Field-Effect Transistors | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Do Hwan | - |
dc.identifier.doi | 10.1021/cm400592b | - |
dc.identifier.scopusid | 2-s2.0-84877750939 | - |
dc.identifier.wosid | 000319184600062 | - |
dc.identifier.bibliographicCitation | CHEMISTRY OF MATERIALS, v.25, no.09, pp.1927 - 1934 | - |
dc.relation.isPartOf | CHEMISTRY OF MATERIALS | - |
dc.citation.title | CHEMISTRY OF MATERIALS | - |
dc.citation.volume | 25 | - |
dc.citation.number | 09 | - |
dc.citation.startPage | 1927 | - |
dc.citation.endPage | 1934 | - |
dc.type.rims | ART | - |
dc.type.docType | 정기학술지(Article(Perspective Article포함)) | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | TRANSPORT | - |
dc.subject.keywordPlus | PHYSICS | - |
dc.subject.keywordAuthor | polymer semiconductor | - |
dc.subject.keywordAuthor | field-effect transistors | - |
dc.subject.keywordAuthor | inkjet-printing | - |
dc.subject.keywordAuthor | X-ray diffraction | - |
dc.subject.keywordAuthor | density of states | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/cm400592b | - |
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