The Hydrodeoxygenation of 2-Methoxyphenol over Ni/Kieselguhr Catalysts as a Model Reaction for Bio-oil Upgrading
- Authors
- Jeon, J. -K.; Huh, B.; Lee, C. H.; Suh, D. J.; Suh, Y. -W.; Heo, H. S.; Park, Y. -K.
- Issue Date
- Feb-2013
- Publisher
- TAYLOR & FRANCIS INC
- Keywords
- bio-oil; hydrodeoxygenation; 2-methoxyphenol; MgO; Ni; kieselguhr
- Citation
- ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, v.35, no.3, pp.271 - 277
- Indexed
- SCIE
SCOPUS
- Journal Title
- ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS
- Volume
- 35
- Number
- 3
- Start Page
- 271
- End Page
- 277
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/163478
- DOI
- 10.1080/15567036.2010.511427
- ISSN
- 1556-7036
- Abstract
- Ni/kieselguhr catalysts were applied to hydrodeoxygenate 2-methoxyphenol as a model reaction for bio-oil upgrading in a batch reactor at 100 degrees C and 1.36 MPa. The Ni(40 wt%)-MgO(1.8 wt%)/kieselguhr showed much higher activity in the 2-methoxyphenol hydrodeoxygenation, which could be attributed to the optimal nickel particle size, surface area, and reducibility of the catalyst. Of the Na2CO3 + Urea, NaHCO3, and (NH4)2CO3 precipitants, the Na2CO3 + Urea showed the highest activity because the dispersion and surface area of nickel, rather than the pore size of the catalyst, seems to play an important role in the 2-methoxyphenol hydrodeoxygenation.
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