Red-emitting materials derived from 2,3-dicyanopyrazine for organic light emitting devices
- Authors
- Jang, Chun Keun; Song, Cheol Jun; Park, Ji Hyun; Yao, Wang; Jaung, Jae Yun
- Issue Date
- Jan-2013
- Publisher
- SAGE PUBLICATIONS LTD
- Keywords
- 2,3-dicyanopyrazine; triphenylamine; organic light-emitting devices; Knoevenagel reaction; computational chemistry; quantum yield; red emitting material
- Citation
- JOURNAL OF CHEMICAL RESEARCH, no.1, pp.57 - 61
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF CHEMICAL RESEARCH
- Number
- 1
- Start Page
- 57
- End Page
- 61
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/163686
- DOI
- 10.3184/174751912X13554011072941
- ISSN
- 1747-5198
- Abstract
- Styryl-substituted derivatives of 2,3-dicyanopyrazine were designed and synthesised by the Knoevenagel condensation of 2,3-dicyano-5-methylpyrazines with 4-(diphenylamino)benzaldehyde for use as red-emitting fluorescent dyes in organic light-emitting devices. Structural analysis of the red-emitting styryl fluorescent dyes was carried out using H-1 NMR, FT-IR, and elemental analysis. The electroluminescent performance of multi-layered organic light-emitting devices fabricated with the triphenylamine-substituted dicyanopyrazine compound as the emitting layer achieved a current efficiency of 1.57 cd A(-1) in the green region with CIE coordinates of (0.37, 0.51). However, the green emission (525 nm) observed from the tris-(8-hydroxyquinolinato)aluminum(III) (Alq(3)) electron-transport layer indicated the action of a recombination phenomenon between the emitting layer and the Alq(3) electron-transport layer. The device fabricated with the tert-butylphenyl-substituted compound achieved a current efficiency of 0.238 cd A(-1) in the red region with CIE coordinates of (0.54, 0.42) and showed no recombination phenomenon.
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