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Magnetically Responsive Inorganic/Polydiacetylene Nanohybrids

Authors
Lee, JoosubYoon, BoraHam, Dae-YoungYarimaga, OktayLee, Chan WooJaworski, JustynKim, Jong-Man
Issue Date
May-2012
Publisher
WILEY-V C H VERLAG GMBH
Keywords
conjugated polymers; magnetite; polydiacetylene; sensors
Citation
MACROMOLECULAR CHEMISTRY AND PHYSICS, v.213, no.9, pp.893 - 903
Indexed
SCIE
SCOPUS
Journal Title
MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume
213
Number
9
Start Page
893
End Page
903
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/165726
DOI
10.1002/macp.201200049
ISSN
1022-1352
Abstract
A direct method for the generation of magnetically responsive conjugated polymer supramolecules is described. By immobilizing magnetite nanoparticles (MNP) on the surface of polydiacetylene (PDA) supramolecules, an inorganic/conjugated polymer hybrid system results that enables the incorporation of an important property (magnetism) to an attractive class of colorimetric PDA sensors. Benefits of this new system include: (1) ease of preparation, (2) variability in diacetylene labeling of MNPs, (3) diversity in conjugated PDA morphologies, (4) facile isolation process, and (5) immobilization of the PDA without altering the colorimetric (sensory) properties. It is demonstrated that PDA/MNP systems offer advantages in applications including film formation, separation, and sensing.
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