Nitrate and ammonium ions removal from groundwater by a hybrid system of zero-valent iron combined with adsorbents
- Authors
- Ji, Min-Kyu; Park, Won-Bae; Khan, Moonis Ali; Abou-Shanab, Reda A. I.; Kim, Yongje; Cho, Yunchul; Choi, Jaeyoung; Song, Hocheol; Jeon, Byong Hun
- Issue Date
- Apr-2012
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- JOURNAL OF ENVIRONMENTAL MONITORING, v.14, no.4, pp.1153 - 1158
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF ENVIRONMENTAL MONITORING
- Volume
- 14
- Number
- 4
- Start Page
- 1153
- End Page
- 1158
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/165841
- DOI
- 10.1039/c2em10911e
- ISSN
- 1464-0325
- Abstract
- Nitrate (NO3-) is a commonly found contaminant in groundwater and surface water. It has created a major water quality problem worldwide. The laboratory batch experiments were conducted to investigate the feasibility of HCl-treated zero-valent iron (Fe-0) combined with different adsorbents as hybrid systems for simultaneous removal of nitrate (NO3-) and ammonium (NH4+) ions from aqueous solution. The maximum NO3- removal in combined Fe-0-granular activated carbon (GAC), Fe-0-filtralite and Fe-0-sepiolite systems was 86, 96 and 99%, respectively, at 45 degrees C for 24 h reaction time. The NO3- removal rate increased with the increase in initial NO3- concentration. The NO3- removal efficiency by hybrid systems was in the order of sepiolite ˃ filtralite ˃ GAC. The NH4+ produced during the denitrification process by Fe-0 was successfully removed by the adsorbents, with the removal efficiency in the order of GAC ˃ sepiolite ˃ filtralite. Results of the present study suggest that the use of a hybrid system could be a promising technology for achieving simultaneous removal of NO3- and NH4+ ions from aqueous solution.
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