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Temperature-induced evolution of novel mixture-phased particles at the tips of SnO2 whiskers

Authors
Kim, Sang SubChoi, Sun-WooLee, ChongmuYang, Ju ChanNa, Han GilKwak, Dong SubKim, Hyoun Woo
Issue Date
Jan-2012
Publisher
Elsevier BV
Keywords
Tin oxide; Nanostructures; Gas sensors; Whiskers
Citation
Chemical Engineering Journal, v.179, pp 381 - 387
Pages
7
Indexed
SCI
SCIE
SCOPUS
Journal Title
Chemical Engineering Journal
Volume
179
Start Page
381
End Page
387
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/166498
DOI
10.1016/j.cej.2011.10.084
ISSN
1385-8947
1873-3212
Abstract
A mixture of Sn, In, and Ge powders was thermally evaporated to synthesize SnO2 whiskers. Elevation of the growth temperature from 800 degrees C to 900 degrees C contributed to the generation of mixture-phased particles at the tips of whickers, due to the change of the dominant growth mechanism from base-growth vapor-liquid-solid (VLS) to a tip-growth VLS process. We observed that the particles were comprised of a mixture of tetragonal SnO2, rhomboheclral In2O3, and hexagonal GeO2. The composite materials exhibited stable and reproducible sensing properties with respect to NO2 and CO.
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