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Catalytic roles of metals and supports on hydrodeoxygenation of lignin monomer guaiacol

Authors
Lee, Cho RimYoon, Ji SunSuh, Young-WoongChoi, Jae-WookHa, Jeong-MyeongSuh, Dong JinPark, Young-Kwon
Issue Date
Jan-2012
Publisher
ELSEVIER
Keywords
Hydrodeoxygenation; Guaiacol; Lignin; Rh/SiO2-Al2O3; Catalyst; Biomass
Citation
CATALYSIS COMMUNICATIONS, v.17, pp.54 - 58
Indexed
SCIE
SCOPUS
Journal Title
CATALYSIS COMMUNICATIONS
Volume
17
Start Page
54
End Page
58
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/166558
DOI
10.1016/j.catcom.2011.10.011
ISSN
1566-7367
Abstract
Hydrodeoxygenation of the lignin monomer guaiacol was performed on the bifunctional catalysts of noble-metals supported on acidic matrices. The catalytic roles of metal nanoparticles and acidic supports were elucidated using the acid-site-measurement-dependent catalysis results, which demonstrated that metals were responsible for the hydrogenation of aromatic rings while metal-deposited acidic supports were indispensable to the deoxygenation of oxygenates. Among various combinations of metals and supports, Rh/SiO2-Al2O3 and Ru/SiO2-Al2O3 exhibited the highest cyclohexane yields.
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