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A photochromic phenoxyquinone based cyanide ion sensor
- Authors
- Park, In Sung; Heo, Eun-Joo; Kim, Jong-Man
- Issue Date
- May-2011
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- Cyanide sensor; Photochromic; Phenoxyquinone
- Citation
- TETRAHEDRON LETTERS, v.52, no.19, pp.2454 - 2457
- Indexed
- SCIE
SCOPUS
- Journal Title
- TETRAHEDRON LETTERS
- Volume
- 52
- Number
- 19
- Start Page
- 2454
- End Page
- 2457
- ISSN
- 0040-4039
- Abstract
- We have developed a new chemosensor system for cyanide ion that is based on a photochromic material. We observed that addition of cyanide anion to a UV irradiated solution of a phenoxynaphthacenequinone derivative brought about a significant change in the absorption spectra that enabled detection of cyanide ion in a selective and sensitive manner. A carbanion intermediate was shown to be responsible for the long wavelength absorption band (630-940 nm) that is generated by cyanide addition.
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Related Researcher
- Kim, Jong Man
- COLLEGE OF ENGINEERING (DEPARTMENT OF CHEMICAL ENGINEERING)