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Study on the Cycling Performance of Li4Ti5O12 Electrode in the Ionic Liquid Electrolytes Containing an Additive
- Issue Date
- Jan-2011
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- Anode; Ionic liquid; Lithium ion battery; Li4Ti5O12; Solid electrolyte interphase
- Citation
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.32, no.1, pp.105 - 108
- Indexed
- SCIE
SCOPUS
KCI
- Journal Title
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY
- Volume
- 32
- Number
- 1
- Start Page
- 105
- End Page
- 108
- ISSN
- 0253-2964
- Abstract
- The cycling behavior of Li4Ti5O12 electrode in the ionic liquid (IL)-based electrolytes containing 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and a small amount of additive (vinylene carbonate, ethylene carbonate, fluoroethylene carbonate) was investigated. The Li4Ti5O12 electrode in the IL electrolyte with an additive exhibited reversible cycling behavior with good capacity retention. Electrochemical impedance spectroscopy and FTIR studies revealed that an electrochemically stable solid electrolyte interphase was formed on the Li4Ti5O12 electrode in the presence of vinylene carbonate and ethylene carbonate during cycling.
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Related Researcher
- Kim, Dong Won
- COLLEGE OF ENGINEERING (DEPARTMENT OF CHEMICAL ENGINEERING)