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The synthesis and optical characterization of quinoxalines bearing 2,2 ': 6 ',2 ''-terpyridine

Authors
Jang, Chun KeunLee, Yong HwanHan, Shin YoungJaung, Jae Yun
Issue Date
Nov-2008
Publisher
Elsevier BV
Keywords
2,2 ': 6 ',2 ''-terpyridine; quinoxaline; chemosensor; heterocycles; chelating; multi-function
Citation
Dyes and Pigments, v.79, no.2, pp 101 - 104
Pages
4
Indexed
SCIE
SCOPUS
Journal Title
Dyes and Pigments
Volume
79
Number
2
Start Page
101
End Page
104
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/171787
DOI
10.1016/j.dyepig.2007.10.012
ISSN
0143-7208
1873-3743
Abstract
4'-(4-{2-[6,7-Bis-dodecyloxy-3-(2-p-substituted phenyl-vinyl)-quinoxalin-2-yl]-vinyl}-phenyl)-[2,2':6',2 ''] terpyridine was prepared by the Horner-Wadsworth -Emmons (HWE) reaction of 4-[2,2':6',2 '']terpyridin-4'-yl-benzaldehyde and quinoxaline derivatives. The absorption and fluorescence maximum of these compounds were observed at 398-443 nm and 484-586 nm, respectively. The compounds were characterized by H-1 NMR spectroscopy and MALDI-TOF-MS, and their recognition properties for metal ions were evaluated using both absorption and emission spectroscopy.
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