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Mass Background Spectra of ICP-MS with Various Acidsopen access

Authors
Nam, Sang-HoChung, HoeilKim, Jae-JinLee, Yong-Ill
Issue Date
Nov-2008
Publisher
WILEY-V C H VERLAG GMBH
Keywords
ICP-MS; Acids; Background; Spectra
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.29, no.11, pp.2237 - 2240
Indexed
SCIE
SCOPUS
KCI
Journal Title
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume
29
Number
11
Start Page
2237
End Page
2240
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/171797
DOI
10.5012/bkcs.2008.29.11.2237
ISSN
0253-2964
Abstract
Background spectra of ICP-MS performed with acid can interfere with the spectra of sample analytes. Thus, we have investigated the background spectra of various acids for use in elemental analysis by argon inductively coupled plasma mass spectrometry. The background spectra for 2% HNO3, 5% HNO3, 5% H2SO4, and 4% CH3COOH were obtained with ICP-MS. This study also shows the possibility of the interference of Na, which could not be from the matrix, but from the ICP-MS sampler. The source of interference of boron was the vibrating glass surface of ultrasonic nebulizer. After a mug cup was kept in 4% CH3COOH for 24 hours, trace Pb was determined with ICP-MS.
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