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Regioselectivities in alkyne activation: synthesis of 2-(bicyclo[3.1.0]hexan-1-yl)furan derivatives by Au-catalyzed cyclization and cyclopropanation
- Authors
- Oh, Chang Ho; Lee, Su Jin; Lee, Ji Ho; Na, Yoon Jung
- Issue Date
- Oct-2008
- Publisher
- Royal Society of Chemistry
- Citation
- Chemical Communications, no.44, pp 5794 - 5796
- Pages
- 3
- Indexed
- SCIE
SCOPUS
- Journal Title
- Chemical Communications
- Number
- 44
- Start Page
- 5794
- End Page
- 5796
- ISSN
- 1359-7345
1364-548X
- Abstract
- 2-Alkynyl-1-cycloalkenecarbaldehydes, in the presence of gold catalysts, undergo aurative cyclization via the 5-exo-dig mode to form Au-carbene intermediates which react with a double bond to form the corresponding cyclopropanes.
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