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Intramolecular Huisgen-type cyclization of platinum-bound pyrylium ions with alkenes and subsequent insertion into a benzylic C-H bond

Authors
Oh, Chang HoLee, Ji HoLee, Sit JinKim, Jae IlHong, Chang Seop
Issue Date
Sep-2008
Publisher
WILEY-BLACKWELL
Keywords
cyclization; homogeneous catalysis; insertion; platinum; pyrylium ions
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.47, no.39, pp.7505 - 7507
Indexed
SCIE
SCOPUS
Journal Title
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume
47
Number
39
Start Page
7505
End Page
7507
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/171862
DOI
10.1002/anie.200802425
ISSN
1433-7851
Abstract
Access granted: The platinum-catalyzed cyclization of enynals 1, which contain an additional alkene bond in their side chain, through a [3+2] cycloaddition to give tetracyclic platinum-carbene complexes A was followed by C-H insertion at the δ position to afford highly complex products 2. These polycyclic compounds and related products of the title transformation are extremely difficult to access by other means. (Chemical Equation Presented).
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