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Palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes
- Authors
- Han, Jin Wook; Hayashi, Tamio
- Issue Date
- Sep-2010
- Publisher
- Pergamon Press Ltd.
- Citation
- Tetrahedron Asymmetry, v.21, no.18, pp 2193 - 2197
- Pages
- 5
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- Tetrahedron Asymmetry
- Volume
- 21
- Number
- 18
- Start Page
- 2193
- End Page
- 2197
- ISSN
- 0957-4166
1362-511X
- Abstract
- Advances in the palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes are presented according to substrate types and chiral monophosphine ligands. Chiral monodentate phosphine ligands with a binaphthyl moiety have been proven to be the most efficient ligands for cyclic 1,3-dienes, and planar chiral ferrocenylmonophosphine ligands with two ferrocenyl moieties for linear 1,3-dienes. The ferrocenylmonophosphine ligands have expanded the substrate scope to 1,3-enynes in the asymmetric hydrosilylation. Palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes and 1,3-enynes leads to the stereoselective synthesis of allylsilanes and allenylsilanes, respectively.
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Related Researcher
- Han, Jin Wook
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)