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Design and Synthesis of Novel Symmetrical Heptamethine Cyanine Chromophores

Authors
Youn, Hye-SooPark, Soo-YoulShin, Seung-RimShin, Joung-IlOh, Seong-GeunJun, KunSon, Young-A
Issue Date
Apr-2010
Publisher
KOREAN FIBER SOC
Keywords
Near-infrared; Cyanine; Optical recording media; Heptamethine; Dyes; Chromophores
Citation
FIBERS AND POLYMERS, v.11, no.2, pp.321 - 323
Indexed
SCIE
SCOPUS
KCI
OTHER
Journal Title
FIBERS AND POLYMERS
Volume
11
Number
2
Start Page
321
End Page
323
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/175185
DOI
10.1007/s12221-010-0321-4
ISSN
1229-9197
Abstract
In this study, near-infrared absorbing dyes, namely new rigidified heptamethine cyanines dyes, were synthesized by the reaction of bis-aldehyde-(1-formyl-3-hydroxymethylene)cyclohexene with 1,1,2-trimethylbenzindole derivatives. Two new rigidified heptamethine cyanine dyes were readily prepared by a novel semi-catalyzed method, considering their potential applications for photodynamic therapy. Absorption properties in near-infrared regions may provide these dyes to be applicable in optical recording media, biological fluorescent stains and probes. Synthesis details and full spectroscopic characterizations of the cyanines were described.
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