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Synthesis of Cyclohexene Derivatives from 1,5-Enynes via Gold-Catalysis and Iodocyclization: A Comparative Study and Applications in the Synthesis of 7/5-or 8/5-Fused Rings and Biarylsopen access

Authors
Lee, YoungunLim, ChoongminKim, SunghwanShin, Seunghoon
Issue Date
Mar-2010
Publisher
KOREAN CHEMICAL SOC
Keywords
Gold catalysis; Iodocyclization; Tandem reaction; 1,5-Enyne; Carbocycles
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.31, no.3, pp.670 - 677
Indexed
SCIE
SCOPUS
KCI
Journal Title
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume
31
Number
3
Start Page
670
End Page
677
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/175385
DOI
10.5012/bkcs.2010.31.03.670
ISSN
0253-2964
Abstract
A comparative study on the Au(I)-catalyzed and IBr-promoted tandem cyclization of 1,5-enyne was reported. This study provides a meaningful mechanistic insight to the concerted nature of this tandem reaction and also provides interesting applications in the synthesis of 7/5- or 8/5-fused bicycles and biaryls.
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