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Stereoselective One-Pot Synthesis of 1-Aminoindanes and 5,6 Fused Azacycles Using a Gold-Catalyzed Redox-Pinacol-Mannich-Michael Cascade
- Authors
- Yeom, Hyun-Suk; Lee, Youngun; Jeong, Jaewon; So, Eunsoo; Hwang, Soojin; Lee, Ji-Eun; Lee, Shim Sung; Shin, Seunghoon
- Issue Date
- Feb-2010
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- carbenoids; cascade reactions; gold; Mannich reactions; redox chemistry
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.49, no.9, pp.1611 - 1614
- Indexed
- SCIE
SCOPUS
- Journal Title
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Volume
- 49
- Number
- 9
- Start Page
- 1611
- End Page
- 1614
- ISSN
- 1433-7851
- Abstract
- "Chemical Equation Presented" Just another Mannich Monday: A cascade intramolecular redox-pinacol-Mannich-Michael reaction sequence catalyzed by gold complexes can be used to generate a variety of structures including spirocycles, 1-aminoindanes, and 5,6-fused azabicycles that have a quaternary carbon center. The reaction is characterized by complete atom-economy, high diastereoselectivity, and remarkable efficiency through tandem reactions.
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Related Researcher
- Shin, Seung hoon
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)