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Thieme Chemistry Journal Awardees - Where Are They Now? Diastereoselective Tandem Iodocarbonate Cyclization of 1,5-Enynes
- Authors
- Lim, Choongmin; Rao, M. Shesha; Shin, Seunghoon
- Issue Date
- Feb-2010
- Publisher
- GEORG THIEME VERLAG KG
- Keywords
- enynes; iodocyclization; IBr; tandem reactions; diastereoselectivity
- Citation
- SYNLETT, no.3, pp.368 - 373
- Indexed
- SCIE
SCOPUS
- Journal Title
- SYNLETT
- Number
- 3
- Start Page
- 368
- End Page
- 373
- ISSN
- 0936-5214
- Abstract
- A diastereoselective, metal-free tandem iodocarbonate-cyclization of 1,5-enyne, emulating the reactivity of gold catalysis is described. The normal selectivity of iodonium reagents for alkene is reversed favoring alkyne activation in the presence of aryl alkynes.
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Related Researcher
- Shin, Seung hoon
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)