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Synthesis and Luminescent Properties of Poly(alkylated indenopyrazine) and Its Copolymer Containing an Alkylated Spirofluorene Moiety

Authors
Kang, Ji SoungKim, Soo-KangJung, Ji-YunLee, Ji-HoonJaung, Jae-YunPark, Jong-Wook
Issue Date
Dec-2009
Publisher
Taylor & Francis
Keywords
blue emitting material; indenopyrazine; OLED; PLED; spirofluorene; Yamamoto polymerization
Citation
Molecular Crystals and Liquid Crystals, v.514, pp 501 - 509
Pages
9
Indexed
SCIE
SCOPUS
Journal Title
Molecular Crystals and Liquid Crystals
Volume
514
Start Page
501
End Page
509
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/175715
DOI
10.1080/15421400903240548
ISSN
1542-1406
1543-5318
Abstract
We have synthesized new alkylated indenopyrazine homopolymer and its copolymer having an alkylated spirofluorene moiety. Poly(6,6,12,12-(Tetra-2-ethylhexyl)-6,12-Dihydrodiindeno[1,2-b: 1,2-e]pyrazine-2,8-diyl) [PEHIP] and Poly(6,6,12,12-(tetra-2-ethylhexyl)-6,12-dihydrodiindeno[1,2-b:1,2-e]pyrazine-co-2',3',6',7'-tertrakis-octyloxy-9-spirofluorene) [PEHIPSF] were polymerized by using Yamamoto reaction. PEHIP and PEHIPSF showed the PL maximum values of 470 nm and 454 nm in PL spectra. The PEHIPSF was fabricated into an EL device and it exhibited the EL maximum value of 463 nm.
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