Synthesis and Luminescent Properties of Poly(alkylated indenopyrazine) and Its Copolymer Containing an Alkylated Spirofluorene Moiety
- Authors
- Kang, Ji Soung; Kim, Soo-Kang; Jung, Ji-Yun; Lee, Ji-Hoon; Jaung, Jae-Yun; Park, Jong-Wook
- Issue Date
- Dec-2009
- Publisher
- Taylor & Francis
- Keywords
- blue emitting material; indenopyrazine; OLED; PLED; spirofluorene; Yamamoto polymerization
- Citation
- Molecular Crystals and Liquid Crystals, v.514, pp 501 - 509
- Pages
- 9
- Indexed
- SCIE
SCOPUS
- Journal Title
- Molecular Crystals and Liquid Crystals
- Volume
- 514
- Start Page
- 501
- End Page
- 509
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/175715
- DOI
- 10.1080/15421400903240548
- ISSN
- 1542-1406
1543-5318
- Abstract
- We have synthesized new alkylated indenopyrazine homopolymer and its copolymer having an alkylated spirofluorene moiety. Poly(6,6,12,12-(Tetra-2-ethylhexyl)-6,12-Dihydrodiindeno[1,2-b: 1,2-e]pyrazine-2,8-diyl) [PEHIP] and Poly(6,6,12,12-(tetra-2-ethylhexyl)-6,12-dihydrodiindeno[1,2-b:1,2-e]pyrazine-co-2',3',6',7'-tertrakis-octyloxy-9-spirofluorene) [PEHIPSF] were polymerized by using Yamamoto reaction. PEHIP and PEHIPSF showed the PL maximum values of 470 nm and 454 nm in PL spectra. The PEHIPSF was fabricated into an EL device and it exhibited the EL maximum value of 463 nm.
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