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Synthesis and optical properties of tetrapyrazinoporphyrazines containing camphorquinone group

Authors
Jang, Chun KeunByun, Seung HwanKim, Song HakLee, Do KyungJaung, Jae Yun
Issue Date
Jul-2009
Publisher
WORLD SCI PUBL CO INC
Keywords
camphorquinone; 2,3-dicyanopyrazine; phthalocyanines; spectral properties; fluorescence; aggregation
Citation
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, v.13, no.7, pp.794 - 797
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume
13
Number
7
Start Page
794
End Page
797
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/176547
DOI
10.1142/S1088424609000991
ISSN
1088-4246
Abstract
2,3-dicyanopyrazine and metallophthalocyanines were synthesized with magnesium containing (+/-)camphorquinone substituent. 2,3-dicyanopyrazine was prepared by condensation reaction of diaminomaleonitrile (DAMN) with 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione (1). The tetrapyrazinoporphyrazine was characterized by a combination of UV-visible spectroscopy, fluorescence spectroscopy, infrared radiation, elemental analysis, MALDI-TOF-MS and H-1 NMR spectroscopy.
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