Synthesis and optical properties of tetrapyrazinoporphyrazines containing camphorquinone group
- Authors
- Jang, Chun Keun; Byun, Seung Hwan; Kim, Song Hak; Lee, Do Kyung; Jaung, Jae Yun
- Issue Date
- Jul-2009
- Publisher
- WORLD SCI PUBL CO INC
- Keywords
- camphorquinone; 2,3-dicyanopyrazine; phthalocyanines; spectral properties; fluorescence; aggregation
- Citation
- JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, v.13, no.7, pp.794 - 797
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
- Volume
- 13
- Number
- 7
- Start Page
- 794
- End Page
- 797
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/176547
- DOI
- 10.1142/S1088424609000991
- ISSN
- 1088-4246
- Abstract
- 2,3-dicyanopyrazine and metallophthalocyanines were synthesized with magnesium containing (+/-)camphorquinone substituent. 2,3-dicyanopyrazine was prepared by condensation reaction of diaminomaleonitrile (DAMN) with 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione (1). The tetrapyrazinoporphyrazine was characterized by a combination of UV-visible spectroscopy, fluorescence spectroscopy, infrared radiation, elemental analysis, MALDI-TOF-MS and H-1 NMR spectroscopy.
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