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Preparation of CaO as OLED getter material through control of crystal growth of CaCO3 by block copolymers in aqueous solution

Authors
Park, Jae-HyungOh, Seong-Geun
Issue Date
Jan-2009
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
Inorganic compounds; Oxides; Crystal growth; X-ray diffraction; Crystal structure
Citation
MATERIALS RESEARCH BULLETIN, v.44, no.1, pp.110 - 118
Indexed
SCIE
SCOPUS
Journal Title
MATERIALS RESEARCH BULLETIN
Volume
44
Number
1
Start Page
110
End Page
118
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/177437
DOI
10.1016/j.materresbull.2008.03.022
ISSN
0025-5408
Abstract
As the starting materials of organic light-emitting diode (OLED) getter, calcium carbonate (CaCO3) particles with various shapes and crystal structures have been successfully prepared with additives (L64 or PEGPG), which contain blocks of poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO). These CaCO3 particles were calcinated into highly crystalline calcium oxide (CaO) nanoparticles with high capacity of water adsorption up to 14.23 wt.%. The CaCO3 and CaO particles prepared at various conditions were characterized using the field emission scanning electron microscopy (FE-SEM), Fourier transform infrared microscopy (FTAR), X-ray powder diffraction (XRD), and dynamic vapor sorption (DVS) method.
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