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Effective Catalytic Activity of the Hydrated Gold Catalyst NaAuCl4 center dot 2H(2)O To Construct Highly Fused Cyclopentenones
- Authors
- Karmakar, Swastik; Kim, Ahyun; Oh, Chang Ho
- Issue Date
- Jan-2009
- Publisher
- GEORG THIEME VERLAG KG
- Keywords
- cyclopentenones; carbocycles; gold catalysis; 1,2-pivaloate shift; Nazarov-type cyclization
- Citation
- SYNTHESIS-STUTTGART, no.2, pp.194 - 198
- Indexed
- SCIE
SCOPUS
- Journal Title
- SYNTHESIS-STUTTGART
- Number
- 2
- Start Page
- 194
- End Page
- 198
- ISSN
- 0039-7881
- Abstract
- The rapid synthesis of various carbocycle-fused highly Substituted cyclopentenones is described to occur via tandem 1,2-shift of pivaloate followed by carbocyclization under the catalysis of the hydrated gold catalyst NaAuCl4 center dot 2H(2)O.
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Related Researcher
- Oh, Chang Ho
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)