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Synthesis of Nanoporous Material from Zeolite USY and Catalytic Application to Bio-Oil Conversion

Authors
Park, Hyun JuJeon, Jong-KiKim, Ji ManLee, Hyung IkYim, Jin-HeongPark, JunhongPark, Young-Kwon
Issue Date
Oct-2008
Publisher
AMER SCIENTIFIC PUBLISHERS
Keywords
MMZ(USY); Catalytic Conversion; Hydrothermal Stability; Phenolics; Deoxygenation; Bio-Oil
Citation
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, v.8, no.10, pp.5439 - 5444
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
Volume
8
Number
10
Start Page
5439
End Page
5444
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/177844
DOI
10.1166/jnn.2008.1102
ISSN
1533-4880
Abstract
A highly ordered nanoporous aluminosilicate (MMZ(USY)) was synthesized using commercially available zeolite USY as the framework source and cetyltrimethylammonium bromide as the template. The aluminosilicate was characterized by XRD, N-2 adsorption, ICP-AES and TPD. The catalytic performance of the MMZ(USY) material in the conversion of bio-oil was compared with that of Al-MCM-41, which was synthesized using a direct sol-gel method. The highly accessible nanopores, hydrothermal stability and the intermediate acidic properties of MMZ(USY) correlated with the catalytic performance in the conversion of the bio-oil. The MMZ(USY) used in this study showed excellent activity, selectivity and stability for the production of desirable organic compounds, such as phenolics, with a high degree of deoxygenation.
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