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Structural and optical properties of chemically synthesized monodispersed CdCr2S4 films

Authors
Todkar, V. V.Mane, Rajaram SakharamLokhande, Chandrakant DnyandevPathan, Habib M.Joo, Oh-ShimChung, HoeilYoon, Moon-YoungHan, Sung Hwan
Issue Date
Jul-2008
Publisher
Pergamon Press Ltd.
Keywords
amorphous materials; thin films; chemical growth; optical properties
Citation
Journal of Physics and Chemistry of Solids, v.69, no.7, pp 1802 - 1807
Pages
6
Indexed
SCIE
SCOPUS
Journal Title
Journal of Physics and Chemistry of Solids
Volume
69
Number
7
Start Page
1802
End Page
1807
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/178185
DOI
10.1016/j.jpcs.2007.12.017
ISSN
0022-3697
1879-2553
Abstract
Alkaline chemical synthesis of amorphous CdCr2S4 (CCS) thin films of different thicknesses using cadmium chloride, chromic acid, disodium salt of ethylenediaminetetra acetic acid and thiourea precursors is reported, and the structural and surface morphological properties of CCS using X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), and transmission electron microscopy (TEM) techniques are discussed. Films of aggregated grains with some void spaces are obtained. Change in band gap energy and electrical resistivity of CCS films are discussed as a function of film thickness. n-type conductivity is confirmed from the sign of thermally generated voltage across the cold and hot junctions.
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