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Electrochemical and thermal characterization of AlF3-coated Li[Ni0.8Co0.15Al0.05]O-2 cathode in lithium-ion cells

Authors
Kim, Hyung-baePark, Byoung-ChulMyung, Seung-TaekAmine, KhalilPrakash, JaiSun, Yang Kook
Issue Date
Apr-2008
Publisher
ELSEVIER SCIENCE BV
Keywords
Li[Ni0.8Co0.15Al0.05]O-2; aluminum fluoride; coating; cathode; lithium battery; capacity retention
Citation
JOURNAL OF POWER SOURCES, v.179, no.1, pp.347 - 350
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF POWER SOURCES
Volume
179
Number
1
Start Page
347
End Page
350
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/178820
DOI
10.1016/j.jpowsour.2007.12.109
ISSN
0378-7753
Abstract
Li[Ni0.8Co0.15Al0.05]O-2 particles are modified with A1F(3) as a new coating material. Even though the initial discharge capacity of the coated Li[Ni0.8Co0.15Al0.05]O-2 is almost the same as that of the pristine material, the capacity retention and the thermal stability, in a highly oxidized state are both significantly improved. This effect is attributed to the thin A1F(3) coating layer protecting the oxidized cathode particles from attack by hydrogen fluoride in the electrolyte.
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