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Hard coating films based on organosilane-modified boehmite nanoparticles under UV/thermal dual curing

Authors
Jeon, Seong JeLee, Jai JoonKim, WoongChang, Tae SunKoo, Sang Man
Issue Date
Apr-2008
Publisher
ELSEVIER SCIENCE SA
Keywords
boehmite znanoparticle; organosilane; hard coating; UV/thermal curing; scanning electron microscopy; wear; infrared spectroscopy
Citation
THIN SOLID FILMS, v.516, no.12, pp.3904 - 3909
Indexed
SCIE
SCOPUS
Journal Title
THIN SOLID FILMS
Volume
516
Number
12
Start Page
3904
End Page
3909
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/178829
DOI
10.1016/j.tsf.2007.07.165
ISSN
0040-6090
Abstract
Hard coating sols and films were prepared for UV/thermal dual curing. The coating sols were composed of boehmite nanoparticles modified with organosilanes (e.g. methacryloxy-propyl trimethoxy silane, vinyl triethoxy silane, and 3-glycidoxy-propyltrimethoxy silane), a formulated initiator, and an inorganic or organic cross-linker as an additive. With this coating solution, hard coating films with a pencil hardness above 8H and transparency above 90% in the visible light range were prepared on poly(methyl methacrylate) substrates. In addition, the coating solution could be quickly cured in 3 5 min at a temperature of 100 degrees C by UV/thermal dual curing. The effects of the additive and initiator on the hardness and transparency of the resulting films are described.
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