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Gold(I)-catalyzed hydroaminative cyclization leading to 2,5-dihydroisoxazole
- Authors
- Yeom, Hyun-Suk; Lee, Eun-Sun; Shin, Seunghoon
- Issue Date
- Sep-2007
- Publisher
- GEORG THIEME VERLAG KG
- Keywords
- 2,5-dihydroisoxazoles; heterocycles; cyclizations gold catalysis; carbenoids
- Citation
- SYNLETT, no.14, pp.2292 - 2294
- Indexed
- SCIE
SCOPUS
- Journal Title
- SYNLETT
- Number
- 14
- Start Page
- 2292
- End Page
- 2294
- ISSN
- 0936-5214
- Abstract
- Gold(I)-catalyzed intramolecular hydroamination of O-propargyl-N-Boc-hydroxylamine is reported. The present method provides a novel, catalytic, and mild approach to 2,5-dihydroisoxazole derivatives. In addition, a mechanism of N-O cleavage as a side reaction as well as desired cyclization is proposed.
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Related Researcher
- Shin, Seung hoon
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)