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A practical gold-catalyzed route to 4-substituted oxazolidin-2-ones from N-Boc propargylamines
- Issue Date
- Jul-2007
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- gold; oxazolidinones; 1,3-allylic interactions; isomerization
- Citation
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2007, no.21, pp.3503 - 3507
- Indexed
- SCIE
SCOPUS
- Journal Title
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Volume
- 2007
- Number
- 21
- Start Page
- 3503
- End Page
- 3507
- ISSN
- 1434-193X
- Abstract
- Au-I-catalyzed cyclization of N-Boc propargylamines into 4-alkylidene oxazolidin-2-ones is described. This modular approach provides access to a variety of nonproteogenic 4-substituted oxazolidinones that are important in asymmetric synthesis and biological applications. The current flexible route is characterized by low catalyst loading, mild conditions, and operational simplicity.
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Related Researcher
- Shin, Seung hoon
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)