A practical gold-catalyzed route to 4-substituted oxazolidin-2-ones from N-Boc propargylamines
- Authors
- Lee, Eun-Sun; Yeom, Hyun-Suk; Hwang, Ji-Hyun; Shin, Seunghoon
- Issue Date
- Jul-2007
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- gold; oxazolidinones; 1,3-allylic interactions; isomerization
- Citation
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2007, no.21, pp.3503 - 3507
- Indexed
- SCIE
SCOPUS
- Journal Title
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Volume
- 2007
- Number
- 21
- Start Page
- 3503
- End Page
- 3507
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/179894
- DOI
- 10.1002/ejoc.200700210
- ISSN
- 1434-193X
- Abstract
- Au-I-catalyzed cyclization of N-Boc propargylamines into 4-alkylidene oxazolidin-2-ones is described. This modular approach provides access to a variety of nonproteogenic 4-substituted oxazolidinones that are important in asymmetric synthesis and biological applications. The current flexible route is characterized by low catalyst loading, mild conditions, and operational simplicity.
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