Significant improvement of electrochemical performance of AlF3-coated Li[Ni0.8Co0.1Mn0.1]O-2 cathode materials
- Authors
- Woo, Si Uk; Yoon, Chong Seung; Amine, Khalil; Belharouak, Ilias; Sun, Yang Kook
- Issue Date
- Jan-2007
- Publisher
- ELECTROCHEMICAL SOC INC
- Citation
- JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.154, no.11, pp.A1005 - A1009
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF THE ELECTROCHEMICAL SOCIETY
- Volume
- 154
- Number
- 11
- Start Page
- A1005
- End Page
- A1009
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/180573
- DOI
- 10.1149/1.2776160
- ISSN
- 0013-4651
- Abstract
- The particle surface of Li[Ni0.8Co0.1Mn0.1]O-2 was modified with AlF3 as a coating material to improve the electrochemical properties. The effect of AlF3 coating on Li[Ni0.8Co0.1Mn0.1]O-2 cathode was extensively studied with respect to the structural and electrochemical properties, and thermal stability. The AlF3 coating on Li[Ni0.8Co0.1Mn0.1]O-2 particles improved the overall electrochemical properties, such as the cyclability, rate capability, and thermal stability, compared to pristine Li[Ni0.8Co0.1Mn0.1]O-2. Electrochemical impedance spectroscopy and transmission electron microscopy showed that the AlF3 coating on Li[Ni0.8Co0.1Mn0.1]O-2 particles played an important role in stabilizing the interface between the cathode and electrolyte.
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