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Gold(I)-catalyzed intramolecular hydroamination of alkyne with trichloroacetimidates
- Authors
- Kang, Ji-Eun; Kim, Hak-Beom; Lee, Jin-Woo; Shin, Seunghoon
- Issue Date
- Aug-2006
- Publisher
- American Chemical Society
- Citation
- Organic Letters, v.8, no.16, pp 3537 - 3540
- Pages
- 4
- Indexed
- SCIE
SCOPUS
- Journal Title
- Organic Letters
- Volume
- 8
- Number
- 16
- Start Page
- 3537
- End Page
- 3540
- ISSN
- 1523-7060
1523-7052
- Abstract
- A study on the gold (I)-catalyzed intramolecular hydroamination of trichloroacetimidates derived from propargyl and homopropargyl alcohols is described. In the presence of 2 - 5 mol % of cationic Au(I) complex, a variety of trichloroacetimidates undergo efficient hydroamination under an exceptionally mild condition. An orthogonality of the current catalytic protocol with those using a stoichiometric electrophile as well as a preliminary synthetic application as a stable precursor of 2-acylamino-1,3-diene has been demonstrated.
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Related Researcher
- Shin, Seung hoon
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)