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Tandem Diels-Alder cycloadditions of 2-pyrone-5-acrylates for the efficient synthesis of novel tetracyclolactones

Authors
Chung, Soo-ImSeo, JoobeomCho, Cheon-Gyu
Issue Date
Aug-2006
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF ORGANIC CHEMISTRY, v.71, no.17, pp.6701 - 6704
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF ORGANIC CHEMISTRY
Volume
71
Number
17
Start Page
6701
End Page
6704
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/181183
DOI
10.1021/jo061119e
ISSN
0022-3263
Abstract
Readily prepared from the regioselective Pd-catalyzed coupling reactions of 3,5-dibromo-2-pyrone, 3-bromo-2-pyrone5-carboxylates undergo tandem uninterrupted sequential Diels-Alder cycloaddition reactions with allyl vinyl ethers in a highly regio- and stereoselective fashion to provide a series of novel tetracyclolactones in good yields.
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