Detailed Information

Cited 0 time in webofscience Cited 0 time in scopus
Metadata Downloads

Highly diastereoselective type-I IMDA reaction forming medium-sized macrolactones

Authors
Shin, Jeong-TaekHong, Sung-ChoShin, SeunghoonCho, Cheon-Gyu
Issue Date
Jul-2006
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, v.8, no.15, pp.3339 - 3341
Indexed
SCIE
SCOPUS
Journal Title
ORGANIC LETTERS
Volume
8
Number
15
Start Page
3339
End Page
3341
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/181262
DOI
10.1021/ol061198g
ISSN
1523-7060
Abstract
Intramolecular Diels-Alder (IMDA) reactions of 2-pyrones containing an alkyne tether occur with remarkably high diastereofacial selectivity to provide medium-sized macrolactones. Because of the strain in the alkyne-tethered macrocyclic system, a single methyl group in the tether provides sufficient conformational bias to generate medium-sized macrocycles with unusually high selectivity.
Files in This Item
Go to Link
Appears in
Collections
서울 자연과학대학 > 서울 화학과 > 1. Journal Articles

qrcode

Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.

Related Researcher

Researcher Cho, Cheon Gyu photo

Cho, Cheon Gyu
COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)
Read more

Altmetrics

Total Views & Downloads

BROWSE