Regioselective [5,5]-sigmatropic rearrangement reactions of aryl hydrazides
- Authors
- Kang, Hong-Min; Lim, Young-Kwan; Shin, In-Jee; Kim, Hee-Yeon; Cho, Cheon-Gyu
- Issue Date
- May-2006
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v.8, no.10, pp.2047 - 2050
- Indexed
- SCIE
SCOPUS
- Journal Title
- ORGANIC LETTERS
- Volume
- 8
- Number
- 10
- Start Page
- 2047
- End Page
- 2050
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/181517
- DOI
- 10.1021/ol060451+
- ISSN
- 1523-7060
- Abstract
- N,N'-Aryl hydrazides with substituents at the ortho or meta positions undergo highly regioselective [5,5]-sigmatropic rearrangement reactions to furnish benzidines in good to excellent isolated yields. The presence of single substituent at either the ortho or meta position provides sufficient bias, effectively suppressing the formation of diphenylene, the major byproduct of the conventional benzidine rearrangement reaction.
- Files in This Item
-
Go to Link
- Appears in
Collections - 서울 자연과학대학 > 서울 화학과 > 1. Journal Articles
![qrcode](https://api.qrserver.com/v1/create-qr-code/?size=55x55&data=https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/181517)
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.