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Reduced Metal Contamination in Atomic-Layer-Deposited HfO2 Films Grown on Si Using O-3 Oxidant Generated Without N-2 Assistance

Authors
Park, Tae JooChung, Keum JeeKim, Hyun-ChulAhn, JinhoWallace, Robert M.Kim, Jiyoung
Issue Date
May-2010
Publisher
ELECTROCHEMICAL SOC INC
Keywords
atomic layer deposition; dielectric thin films; electric breakdown; elemental semiconductors; etching; hafnium compounds; impurities; oxidation; silicon; stainless steel
Citation
ELECTROCHEMICAL AND SOLID STATE LETTERS, v.13, no.8, pp.G65 - G67
Indexed
SCIE
SCOPUS
Journal Title
ELECTROCHEMICAL AND SOLID STATE LETTERS
Volume
13
Number
8
Start Page
G65
End Page
G67
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/182049
DOI
10.1149/1.3430657
ISSN
1099-0062
Abstract
The physicochemical and electrical properties of atomic-layer-deposited HfO2 films grown using O-3 generated with and without N-2 assistance were examined. Compared to the films grown using conventionally generated O-3 with N-2 assistance, the HfO2 film grown using O-3 generated without N-2 assistance had less metal impurities (mainly Cr) possibly due to the etching of stainless ozone delivery line. This induced a higher physical density of the film and a lower Si concentration in the film, which resulted in enhanced dielectric properties and reliability such as dielectric breakdown and resistance to constant voltage stress. (C) 2010 The Electrochemical Society. [DOI: 10.1149/1.3430657] All rights reserved.
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