Facile Green Synthesis of Pseudocapacitance-Contributed Ultrahigh Capacity Fe-2(MoO4)(3) as an Anode for Lithium-Ion Batteries
- Authors
- Huu, Ha Tran; Im, Won Bin
- Issue Date
- Aug-2020
- Publisher
- AMER CHEMICAL SOC
- Keywords
- pseudocapacitance; anode; lithium-ion batteries; water droplet-assisted solid-state reaction; ultrahigh capacity
- Citation
- ACS APPLIED MATERIALS & INTERFACES, v.12, no.31, pp.35152 - 35163
- Indexed
- SCIE
SCOPUS
- Journal Title
- ACS APPLIED MATERIALS & INTERFACES
- Volume
- 12
- Number
- 31
- Start Page
- 35152
- End Page
- 35163
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/1823
- DOI
- 10.1021/acsami.0c11862
- ISSN
- 1944-8244
- Abstract
- The investigation into the use of earth-abundant elements as electrode materials for lithium-ion batteries (LIBs) is becoming more urgent because of the high demand for electric vehicles and portable devices. Herein, a new green synthesis strategy, based on a facile solid-state reaction with the assistance of water droplets' vapor, was conducted to prepare Fe-2(MoO4)(3) nanosheets as anode materials for LIBs. The obtained sample possesses a two-dimensional stacked nanosheet construction with open gaps providing a much higher surface area compared to the bulk sample conventionally synthesized. The nanosheet sample delivers an ultrahigh reversible capacity (1983.6 mA h g(-1)) at a current density of 100 mA g(-1) after 400 cycles, which could be related to the contribution of pseudocapacitance. The enhancement in cyclability and rated performance with an interesting increased capacity could be caused by the effect of electrochemical milling and the in situ formation of metallic particles in its lithium-ion storage mechanism.
- Files in This Item
-
Go to Link
- Appears in
Collections - 서울 공과대학 > 서울 신소재공학부 > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.