Recent Catalytic Advances on the Sustainable Production of Primary Furanic Amines from the One-Pot Reductive Amination of 5-Hydroxymethylfurfural
- Authors
- Truong, Cong Chien; Mishra, Dinesh Kumar; Suh, Young-Woong
- Issue Date
- Jan-2023
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- 5-hydroxymethylfurfural; biomass; heterogeneous catalysis; reductive amination; sustainable chemistry
- Citation
- CHEMSUSCHEM, v.16, no.1, pp.1 - 14
- Indexed
- SCIE
SCOPUS
- Journal Title
- CHEMSUSCHEM
- Volume
- 16
- Number
- 1
- Start Page
- 1
- End Page
- 14
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/185183
- DOI
- 10.1002/cssc.202201846
- ISSN
- 1864-5631
- Abstract
- 5-Hydroxymethylfurfural (5-HMF) represents a well-known class of lignocellulosic biomass-derived platform molecules. With the presence of many reactive functional groups in the structure, this versatile building block could be valorized into many value-added products. Among well-established catalytic transformations in biorefinery, the reductive amination is of particular interest to provide valuable N-containing compounds. Specifically, the reductive amination of 5-HMF with ammonia (NH3) and molecular hydrogen (H-2) offers a straightforward and sustainable access to primary furanic amines [i. e., 5-hydroxymethyl-2-furfuryl amine (HMFA) and 2,5-bis(aminomethyl)furan (BAMF)], which display far-reaching utilities in pharmaceutical, chemical, and polymer industries. In the presence of heterogeneous catalysts contanining monometals (Ni, Co, Ru, Pd, Pt, and Rh) or bimetals (Ni-Cu and Ni-Mn), this elegant pathway enables a high-yielding and chemoselective production of HMFA/BAMF compared to other synthetic routes. This Review aims to present an up-to-date highlight on the supported metal-catalyzed reductive amination of 5-HMF with elaborate studies on the role of metal, solid support, and reaction parameters. Besides, the recyclability/adaptability of catalysts as well as the reaction mechanism are also provided to give valuable insights into this potential 5-HMF valorization strategy.
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