Various synthetic approaches for [6,7,m]-tricyclic compounds containing an oxygen-bridged skeleton
- Authors
- Kang, Juyeon; Oh, Chang Ho
- Issue Date
- Feb-2023
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- [6; 7; m]-tricyclic compound; Au catalyst; iodine; oxacyclic compound; oxygen
- Citation
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.44, no.2, pp.163 - 167
- Indexed
- SCIE
SCOPUS
KCI
- Journal Title
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY
- Volume
- 44
- Number
- 2
- Start Page
- 163
- End Page
- 167
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/185226
- DOI
- 10.1002/bkcs.12642
- ISSN
- 0253-2964
- Abstract
- We report the synthesis of [6,7,5]-tricyclic compounds containing an oxabicyclo [3.2.1] octane system from 1,6-enyne carbonyl. We also synthesized [6,7,6]-tricyclic compound from 1,7-enyne carbonyl through Au-catalyzed cyclization. The synthesis of oxacyclic compounds using iodine or oxygen is environmentally friendly cyclization methods. Oxacyclic compounds are useful for synthesizing various diterpene alkaloids.
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