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Various synthetic approaches for [6,7,m]-tricyclic compounds containing an oxygen-bridged skeleton

Authors
Kang, JuyeonOh, Chang Ho
Issue Date
Feb-2023
Publisher
WILEY-V C H VERLAG GMBH
Keywords
[6; 7; m]-tricyclic compound; Au catalyst; iodine; oxacyclic compound; oxygen
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.44, no.2, pp.163 - 167
Indexed
SCIE
SCOPUS
KCI
Journal Title
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume
44
Number
2
Start Page
163
End Page
167
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/185226
DOI
10.1002/bkcs.12642
ISSN
0253-2964
Abstract
We report the synthesis of [6,7,5]-tricyclic compounds containing an oxabicyclo [3.2.1] octane system from 1,6-enyne carbonyl. We also synthesized [6,7,6]-tricyclic compound from 1,7-enyne carbonyl through Au-catalyzed cyclization. The synthesis of oxacyclic compounds using iodine or oxygen is environmentally friendly cyclization methods. Oxacyclic compounds are useful for synthesizing various diterpene alkaloids.
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