Brønsted Acid Doping of P3HT with Largely Soluble Tris(pentafluorophenyl)borane for Highly Conductive and Stable Organic Thermoelectrics Via One-Step Solution Mixing
- Authors
- Suh, Eui Hyun; Oh, Jong Gyu; Jung, Jaemin; Noh, Sung Hoon; Lee, Taek Seong; Jang, Jaeyoung
- Issue Date
- Dec-2020
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- Brønsted acids; molecular doping; organic thermoelectrics; tris(pentafluorophenyl)borane; type II polymorphs
- Citation
- ADVANCED ENERGY MATERIALS, v.10, no.47, pp.1 - 12
- Indexed
- SCIE
SCOPUS
- Journal Title
- ADVANCED ENERGY MATERIALS
- Volume
- 10
- Number
- 47
- Start Page
- 1
- End Page
- 12
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/185455
- DOI
- 10.1002/aenm.202002521
- ISSN
- 1614-6832
- Abstract
- Molecular doping is essential for improving the thermoelectric properties of conjugated polymers, but dopants of low solubility either restrict the formation of high quality films or complicate fabrication steps. Although a highly soluble molecular dopant, tris(pentafluorophenyl)borane (BCF), has been sporadically studied, its potential has not yet been fully explored. Herein, particularly intriguing effects of Brønsted acid doping with BCF-water complexes for poly(3-hexylthiophene) (P3HT) are reported, which can facilitate substantial increases in electrical and thermoelectric properties with remarkable doping stabilities. Interestingly, a unique polymorph of P3HT with interdigitated alkyl chains (called type II) is observed in the Brønsted acid doping with BCF-water complexes. Moreover, the doped P3HT shows conformational change to the quinoid structure, enabling increased backbone planarity. As a result, the Brønsted acid-doped P3HT films exhibit outstanding electrical conductivities, thermoelectric power factors, and figure-of-merit of up to 33.0 S cm−1, 28.3 µW m−1 K−2, and 0.034, respectively. These values are at least an order of magnitude higher than those of P3HT films doped with a conventional molecular dopant, 7,7,8,8-tetracyano-2,3,5,6-tetrafluoroquinodimethane. The Brønsted acid doping with BCF-water complexes also affords excellent air stabilities of P3HT films, which potentially provides a strong comparative advantage over existing highly reactive salt-type dopants, such as FeCl3.
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