Enhanced catalytic conversion of 5-hydroxymethylfurfural to 2,5-diformylfuran by HKUST-1/TEMPO under microwave irradiation
- Authors
- Lin, Jia-Yin; Thanh, Bui Xuan; Kwon, Eilhann; Lin, Kun-Yi Andrew
- Issue Date
- Dec-2021
- Publisher
- SPRINGER HEIDELBERG
- Keywords
- 5-Hydroxymethylfurfural; 2; 5-Diformylfuran; HKUST-1; TEMPO; Microwave
- Citation
- BIOMASS CONVERSION AND BIOREFINERY, v.11, no.6, pp.2829 - 2836
- Indexed
- SCIE
SCOPUS
- Journal Title
- BIOMASS CONVERSION AND BIOREFINERY
- Volume
- 11
- Number
- 6
- Start Page
- 2829
- End Page
- 2836
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/190155
- DOI
- 10.1007/s13399-020-00648-7
- ISSN
- 2190-6815
- Abstract
- For developing more effective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF), a Cu-based metal organic framework, HKUST-1, is proposed to incorporate with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) under microwave (MW) for enhancing HMF oxidation to DFF. In comparison to oxidation of HMF by a conventional heating (CH), MW is validated to shorten reaction time (< 1 h) and enhance HMF conversion (> 99%) and yield of DFF (> 99%). HKUST-1 is reusable for HMF conversion using MW over multiple cycles. These results indicate that HKUST-1 is a highly effective catalyst for HMF conversion, and MW further enhances HMF conversion and increases yield of DFF significantly.
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