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Toward High-Safety Potassium-Sulfur Batteries Using a Potassium Polysulfide Catholyte and Metal-Free Anode

Authors
Hwang, Jang-YeonKim, Hee MinYoon, Chong SeungSun, Yang Kook
Issue Date
Mar-2018
Publisher
American Chemical Society
Citation
ACS Energy Letters, v.3, no.3, pp.540 - 541
Indexed
SCIE
SCOPUS
Journal Title
ACS Energy Letters
Volume
3
Number
3
Start Page
540
End Page
541
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/190902
DOI
10.1021/acsenergylett.8b00037
ISSN
2380-8195
Abstract
Based on the reversible conversion reactions, K2Sx (S <= x <= 6) ->(discharge) K2S3 ->(charge) K2S5, discharge charge the proposed K-S battery delivered a high discharge capacity of similar to 400 mAh g(-1) at 0.1 C -rate with stable cycle retention (94% after 20 cycles) and good rate capability up to 2 C -rate. In addition, instead of an explosive and highly reactive potassium metal electrode, a full cell consisting of an electrochemically potassium -impregnated hard carbon and the K2Sx (5 <= x <= 6) catholyte was constructed to demonstrate the feasibility of a safe K S battery system free of metallic potassium.
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서울 공과대학 > 서울 신소재공학부 > 1. Journal Articles
서울 공과대학 > 서울 에너지공학과 > 1. Journal Articles

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