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Synthesis of the Icetexane Diterpenoids (±)-Rosmaridiphenol, (±)-Pisiferin, and (±)-Barbatusol from Abietane
- Authors
- Le, Thuy Quynh; Lee, JuHui; Oh, Chang Ho
- Issue Date
- Jun-2022
- Publisher
- Georg Thieme Verlag
- Keywords
- abietane; barbatusol; diterpenoids; icetexane; pisiferin; ring expansion; rosmaridiphenol
- Citation
- Synlett, v.33, no.10, pp.983 - 987
- Indexed
- SCIE
SCOPUS
- Journal Title
- Synlett
- Volume
- 33
- Number
- 10
- Start Page
- 983
- End Page
- 987
- ISSN
- 0936-5214
- Abstract
- We report the rearrangement of abietane core with trifluoromethanesulfonic anhydride in pyridine to afford the icetexane core, a key intermediate for total syntheses of the structurally intriguing and biologically active compounds (±)-barbatusol, (±)-rosmaridiphenol, and (±)-pisiferin.
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Related Researcher
- Oh, Chang Ho
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)