Cu-doped TiO2 nanofibers coated with 1T MoSe2 nanosheets providing a conductive pathway for the electron separation in CO2 photoreduction
- Authors
- Khan, Haritham; Pawar, Rajendra C.; Charles, Hazina; Lee, Caroline Sunyong
- Issue Date
- Nov-2023
- Publisher
- ELSEVIER
- Keywords
- Cu-doped TiO 2 NFs; CO 2 photoreduction; UV-vis light irradiation; S-Scheme
- Citation
- APPLIED SURFACE SCIENCE, v.636, pp.1 - 13
- Indexed
- SCIE
SCOPUS
- Journal Title
- APPLIED SURFACE SCIENCE
- Volume
- 636
- Start Page
- 1
- End Page
- 13
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/191255
- DOI
- 10.1016/j.apsusc.2023.157832
- ISSN
- 0169-4332
- Abstract
- Efficient solar-driven conversion of CO2 into valuable chemical energy offers a promising way to address the issues of energy shortage and climate change. However, the weak and slow charge kinetics severely impede CO2 photoreduction. Herein, hybrid-phase MoSe2 (1 T-2H MoSe2) nanosheet-coated Cu-doped TiO2 nanofibers (CuTiO2 NFs) were prepared using a solvothermal method. Different characterizations confirmed the successful doping of Cu into a TiO2 crystal lattice and the generation of stable 1 T-2H MoSe2 in the composite samples. The developed internal electric field drives electrons from the Cu-TiO2 NFs to MoSe2, demonstrating the presence of a Step-scheme (S-scheme) charge transfer path in the Cu-TiO2 NFs/1T-2H MoSe2 heterostructure, which allows efficient and selective CO2 photoreduction. In addition, the optimum sample contains an abundant 1 T MoSe2 coupled with Cu+/Cu0 which offers copious active sites to improve CO2 adsorption and subsequent conversion to CO and CH4. The optimum sample exhibits a remarkable CO2 selectivity of 90%. These findings provide new possibilities for improving the preparation of efficient photocatalysts for the photoreduction of CO2.
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