Detailed Information
Cited 0 time in 
Cited 0 time in 
Cited 0 time in
Metadata Downloads
Meso-Free Boron(III)subchlorin and Its μ‑Oxo Dimer with Interacting Chromophores
- Authors
- Chandra, Brijesh; Soman, Rahul; BIJIGIRI SATHISH KUMAR; Kumar, B. Sathish; Jose, K. V. Jovan; Panda, Pradeepta K
- Issue Date
- Dec-2020
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v.22, no.24, pp.9735 - 9739
- Indexed
- SCIE
SCOPUS
- Journal Title
- ORGANIC LETTERS
- Volume
- 22
- Number
- 24
- Start Page
- 9735
- End Page
- 9739
- ISSN
- 1523-7060
- Abstract
- Meso-free B(III)subchlorin 1 has been realized exclusively for the first time from meso-ethoxycarbonyl-substituted tripyrrane along with the first subchlorin dimer 2 as its mu-oxo analogue via a facile one-pot approach. The subchlorin is highly stable toward oxidation; hence, it was not contaminated with the corresponding subporphyrin analogue 3. The subchlorin (56%) and its dimer (30%) exhibit singlet oxygen generation ability for the first time. The B-O-B dimer displays strong exciton coupling between the two macrocycles.
- Files in This Item
- Go to Link
- Appears in
Collections - ETC > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
Related Researcher
- KUMAR, BIJIGIRI SATHISH
- 서울 부총장(서울) (서울 창의융합교육원)