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3,6,13,16-Tetrasubstituted Porphycene: The Missing Link in Porphycene Chemistry
- Issue Date
- Sep-2020
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v.22, no.18, pp.7175 - 7180
- Indexed
- SCIE
SCOPUS
- Journal Title
- ORGANIC LETTERS
- Volume
- 22
- Number
- 18
- Start Page
- 7175
- End Page
- 7180
- ISSN
- 1523-7060
- Abstract
- We have introduced the first 3,6,13,16-tetrasubstituted porphycene as its tetramethoxy analogue. This substitution pattern is one of the most general patterns yet missing in this isomeric porphyrin chemistry. This porphycene exhibits intense fluorescence along with the ability to coordinate with divalent metal ions; in particular, it forms the first stable Zn(II) complex among the tetrasubstituted porphycenes. Notably, the molecular structure of Zn1Py displays supramolecular chirality. © 2020 American Chemical Society.
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Related Researcher
- KUMAR, BIJIGIRI SATHISH
- 서울 부총장(서울) (서울 창의융합교육원)