Exploring the use of butadiene rubbers as a binder in composite cathodes for all-solid-state lithium batteries
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Young-Jun | - |
dc.contributor.author | Hong, Seung-Bo | - |
dc.contributor.author | Kim, Dong Won | - |
dc.date.accessioned | 2023-10-04T06:35:50Z | - |
dc.date.available | 2023-10-04T06:35:50Z | - |
dc.date.created | 2023-04-06 | - |
dc.date.issued | 2023-06 | - |
dc.identifier.issn | 1226-086X | - |
dc.identifier.uri | https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/191594 | - |
dc.description.abstract | Among the various next-generation battery systems, all-solid-state lithium batteries (ASSLBs) employing sulfide-based solid electrolytes have garnered considerable attention because of their high energy density and enhanced safety compared to conventional lithium-ion batteries (LIBs) with liquid electrolytes. The fabrication of composite cathodes for ASSLBs by the wet-slurry process is highly desirable, because it can be scaled into a large sheet and be applied to the established slurry-processed electrode manufacturing technology of LIBs. A polymer binder in the composite cathode is an important component for maintaining good interfacial contacts among the electrode components (active material, solid electrolyte, and conducting carbon) during charge and discharge cycles. In this study, we used polybutadiene and acrylonitrile-butadiene rubbers (NBR) with different acrylonitrile (AN) contents as a polymer binder in the composite cathode. Our results demonstrated that a composite cathode employing NBR with 25 wt.% AN (NBR25) showed good elastic properties and superior adhesion without the large deterioration of interfacial contacts during cycling. The solid-state Li-In/Li6PS5Cl/LiNi0.7Co0.1Mn0.2O2 cell assembled with the composite cathode employing NBR25 exhibited an initial discharge capacity of 149.0 mAh g−1 with good capacity retention at 0.2 C and 25 °C. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE INC | - |
dc.title | Exploring the use of butadiene rubbers as a binder in composite cathodes for all-solid-state lithium batteries | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Dong Won | - |
dc.identifier.doi | 10.1016/j.jiec.2023.02.034 | - |
dc.identifier.scopusid | 2-s2.0-85149686686 | - |
dc.identifier.wosid | 000981954000001 | - |
dc.identifier.bibliographicCitation | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v.122, no.25, pp.341 - 348 | - |
dc.relation.isPartOf | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | - |
dc.citation.title | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | - |
dc.citation.volume | 122 | - |
dc.citation.number | 25 | - |
dc.citation.startPage | 341 | - |
dc.citation.endPage | 348 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART002968064 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | HIGH POLAR POLYACRYLONITRILE | - |
dc.subject.keywordPlus | LI-ION BATTERY | - |
dc.subject.keywordPlus | ELECTROCHEMICAL PERFORMANCE | - |
dc.subject.keywordPlus | ARGYRODITE LI6PS5CL | - |
dc.subject.keywordPlus | ELECTROLYTE | - |
dc.subject.keywordPlus | PROPERTY | - |
dc.subject.keywordAuthor | All-solid-state lithium battery | - |
dc.subject.keywordAuthor | Sulfide solid electrolyte | - |
dc.subject.keywordAuthor | Polymer binder | - |
dc.subject.keywordAuthor | Composite cathode | - |
dc.subject.keywordAuthor | Wet-slurry process | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S1226086X23001181?via%3Dihub | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
222, Wangsimni-ro, Seongdong-gu, Seoul, 04763, Korea+82-2-2220-1365
COPYRIGHT © 2021 HANYANG UNIVERSITY.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.