Electrically conductive metal oxide-Assisted multifunctional separator for highly stable Lithium-Metal batteriesopen access
- Authors
- Kim, Junghwan; Kwon, Kihwan; Roh, Kwangchul; Kwon, Jiseok; Song, Taeseup; Kim, Patrick Joohyun; Choi, Junghyun
- Issue Date
- Sep-2023
- Publisher
- Elsevier Inc.
- Keywords
- Enhanced electrical conductivity; Functionalized separator; Li ion redistribution; Li-metal batteries; Niobium oxide
- Citation
- Electrochemistry Communications, v.154, pp.1 - 6
- Indexed
- SCIE
SCOPUS
- Journal Title
- Electrochemistry Communications
- Volume
- 154
- Start Page
- 1
- End Page
- 6
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/192939
- DOI
- 10.1016/j.elecom.2023.107558
- ISSN
- 1388-2481
- Abstract
- Lithium (Li) metal anodes have received intensive attention owing to its high specific capacity and low redox potential. However, chronic issues related to dendritic Li growth have hindered the pragmatic use of Li-metal batteries (LMBs). As one of feasible approaches, depositing a functional material on the separator is an efficient strategy for improving the electrochemical stability of LMBs. In this paper, we report a functionalized separator, comprising a nitrided niobium dioxide (named as n-NbO2) and a polypropylene (PP) separator. It is identified that niobium oxide interact with metallic Li, resulting in redistributing the localized Li ion. The n-NbO2-coated separator with enhanced electrical conductivity promotes Li plating/stripping process, reinforcing the Li ion redistribution effect. Due to these properties, Li-Cu cells with the n-NbO2-coated separator show the most outstanding cycle stability with high Coulombic efficiency (CE) over 200 cycles.
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