Electron transfer-mediated enhancement of superoxide radical generation in fenton-like process: Key role of oxygen vacancy-regulated local electron density of cobalt sites

Abstract

Designing metal oxides with oxygen vacancy (OV) is a prospective strategy for boosted Fenton-like process. However, what OV is, whether OV enhancement increases the catalytic performance, OV-related H2O2 activation, and relationship between OV and ROS or non-radical pathways have not been fully understood. Herein, yolk-shell Co3O4 nanospheres with various OV were fabricated to overcome the above contentious problems and establish a relationship between OV, ROS, and electron transfer in sulfadiazine (SDZ) degradation via H2O2 activation. The results showed that the delocalized electron-rich Co sites around OV with increasing OV allowed the improved conductivity, thereby leading to stronger adsorption and activation of H2O2 to generate more •OH as evidenced by the attenuated adsorption energy and prolonged O-O bond. The subsequent rapid depletion of •OH coupled with the increase in O2•− over time and the emergence of electron transfer from SDZ explored a pathway enhancing O2•− generation for SDZ degradation.