Nitrogen-doped carbon dot threads as a "turn-off" fluorescent probe for permanganate ions and its hydrogel hybrid as a naked eye sensor for gold(III) ions

Abstract

Highly fluorescent nitrogen-doped carbon dot (NCD) threads were synthesized via simple pyrolysis of citric acid, p-hydroxybenzoic acid, and ammonia. The NCDs show excitation-independent behavior with maximum excitation and emission wavelengths of 350 nm and 435 nm, respectively. The developed probe was used as a turn-off fluorescent sensor for the selective and sensitive determination of permanganate ions in aqueous media. The probe’s hydrogel hybrid displayed a beautiful purple color demonstrating its potential as a naked eye sensor for gold detection. The ratiometric sensor exhibited excellent selectivity towards permanganate ions over 27 other ions with a linear range of 510 nM to 2 μM, a detection limit of 170 nM, and a linear regression value (R2) of 0.9944. Similarly, the linear range and limit of detection for gold ions was 3.89–20 μM and 1.285 μM, respectively. The synthesized NCDs were also used as a fluorescent ink as well as a naked eye marker in association with a gold solution demonstrating its potential forensic and anti-counterfeiting applications.