Control-oriented multiphysics model of a lithium-ion battery for thermal runaway estimation under operational and abuse conditions

Abstract

This study proposes a control-oriented multiphysics model for lithium-ion batteries (LIBs) that can estimate electrochemical-thermal responses in real time under normal operation and abuse conditions. The proposed model integrates the simplified electrochemical model, the thermal resistance network, and the adaptive time-stepping method to ensure computational efficiency without sacrificing the accuracy. Specifically, the diffusion equation of the electrochemical model is simplified by addressing Padé approximation. The thermal resistance network estimates 3D temperature distribution through simple matrix multiplication to account for the entropic, ohmic, and chemical reaction during thermal runaway. The adaptive time-stepping method further secures accurate yet fast explicit calculation. Quantitative experimental validation reveals the high accuracy and robustness, and fast inference time of the proposed model to estimate the electrochemical-thermal responses with the average inference time of 0.0047 s per step. The application of the proposed model on the 26650 LFP cell also demonstrates the versatility on various shapes and types of LIBs. The systematic analysis on the 3D temperature distribution in the LIB of interest not only confirms the effectiveness of the internal temperature monitoring but also ensures the virtual sensing capability. The versatility of the proposed model underscores both design- and control- enabling solutions for battery thermal management.