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수용액 중에서 Ni(II) 이온과 2-(2-Hydroxyethylamino)-2-(hydroxymethyl)-1,3-propanediol(Monotris)과의 착물형성에 대한 연구A Study on the Complexation of Nickel(II) Ion with 2-(2-Hydroxyethylamino)-2-(hydroxymethyl)-1,3-propanediol(Monotris) in Aqueous Solution

Other Titles
A Study on the Complexation of Nickel(II) Ion with 2-(2-Hydroxyethylamino)-2-(hydroxymethyl)-1,3-propanediol(Monotris) in Aqueous Solution
Authors
홍경희심승보오성근전용진
Issue Date
Dec-2010
Publisher
한국산학기술학회
Keywords
Potentiometric; Deprotonated dinuclear complex. NiL2+; Ni2L2H-3+
Citation
한국산학기술학회논문지, v.11, no.12, pp 5221 - 5231
Pages
11
Indexed
KCI
Journal Title
한국산학기술학회논문지
Volume
11
Number
12
Start Page
5221
End Page
5231
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/203297
DOI
10.5762/KAIS.2010.11.12.5221
ISSN
1975-4701
2288-4688
Abstract
Ni(II)이온과 2-(2-Hydroxyethylamino)-2-(hydroxymethyl)-1,3-propanediol(Monotris)과의 착물형성을 25℃ 이온강도 0.10M 에서 전위차법으로 연구하였다. NiL2+ 착물은 히드록실기의 산소 원자 뿐만아니라 아민의 질소기도 금속에 배위하였다. pH가 증가하면서 NiL2=는 3개의 수소이온이 해리된 Ni2L2H-3+의 이핵착물이 형성되었다.
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